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→ System 02 / Demineralized Water

Ultra-pure water, many ways.

Boiler feed, process duty, semiconductor, pharma — the cleanest water in the plant. Each stage has multiple technology paths. Toggle the configuration; click any node to open it.

Pre-treatment
Bulk demin
Polishing
PRE-TREATMENT BULK DEMIN POLISHING BREAK STORAGE Raw Water MMF UF ABF AC SAC DEG SBA Ion Exchange PASS 1 PASS 1 PASS 2 PASS 2 Reverse Osmosis Break Mixed Bed + EDI Storage ACID CAUSTIC Regen Skid pH 6.5–9 Wastewater
→ Reference / Performance benchmarks

What "good" looks like.

Typical operating envelopes from raw-water inlet through to point-of-use distribution. Polishing-stage targets get aggressive — measured in parts per billion, not parts per million.

Indicator
Typical range
Why it matters
Pre-treatment SDI
< 3
Silt Density Index. Above 5 and RO membrane fouling rate climbs steeply.
Free Cl₂ after carbon
< 0.1 ppm
Free chlorine destroys polyamide RO membranes and oxidises IX resin. Carbon must remove it.
RO permeate conductivity
10 – 50 µS/cm (1-pass) · < 5 (2-pass)
Salt rejection × feed conductivity. Trend up = scaling, fouling, or membrane damage.
RO recovery
75 – 85 %
Permeate ÷ feed. Higher recovery = less reject, but scaling risk on concentrate side rises.
IX outlet conductivity
< 10 µS/cm
Throughput indicator. Sharp rise → resin near exhaustion, regen due.
Polished conductivity
< 0.1 µS/cm
After MB or EDI. Equivalent to ultra-pure water (resistivity > 10 MΩ·cm).
Polished silica
< 10 ppb
Critical for high-pressure boilers — silica volatilises with steam and deposits on turbine blades.
Polished sodium
< 2 ppb
Sodium leakage from MB or cation breakthrough indicator. Key for power-plant chemistry.
Storage tank conductivity
< 0.2 µS/cm
Atmospheric CO₂ in-leakage drives this up. N₂ blanket if requirement is < 0.1.
TOC (organics)
< 50 ppb
Organic carryover poisons resin and affects high-purity downstream uses (semiconductor, pharma).
→ Reference / Failure modes

Where it goes wrong.

Six failure families. The rule that sticks: most polishing-stage problems are really upstream feed-water problems in disguise. Test cheap upstream hypotheses first.

→ Membrane fouling

RO performance loss

Tells: rising ΔP across stages, normalized permeate flow drop, salt rejection drop. Layer: feed-water quality. Fix: SDI check, antiscalant audit, CIP with acid then caustic, autopsy a lead module if persistent.

→ Resin fouling

IX capacity decline

Tells: shorter run lengths between regens, conductivity creep at outlet. Layer: feed-water (organics, iron) or regen quality. Fix: resin sample analysis, increase regen dose / time, NaCl / NaOH brine wash for organic foulant.

→ Sodium leak

Cation breakthrough

Tells: sodium analyser climbs from ppb to ppm. Layer: cation resin or MB regen. Fix: check cation regen efficiency, MB resin separation procedure, consider EDI upgrade if recurring.

→ Silica creep

Anion / EDI weakness

Tells: silica analyser trending up at point-of-use. Layer: anion resin or EDI feed quality. Fix: anion regen with hot caustic, EDI feed conductivity check, downstream carbon dioxide check.

→ CO₂ ingress

Storage tank conductivity

Tells: distribution conductivity creeps up overnight, lower at high turnover. Layer: tank vent. Fix: install / restore N₂ blanket, vent filter integrity check, air-gap design audit.

→ Regen sequence

Operator / valve error

Tells: poor regen efficiency, conductivity bump on return-to-service, pH spike at wastewater. Layer: SOP / DCS. Fix: stroke-test regen valves, verify sequence in logic, retrain on regen procedure.

→ Reference / Technology trade-offs

Same function, multiple paths.

Almost every stage of a demin train has competing technologies that produce roughly the same outcome. The right pick depends on feed-water variability, capex vs opex posture, HSE constraints (chemical handling), water scarcity (recovery), and the existing plant footprint. Below: every redundant technology I have seen in the field, tabulated.

Bulk filtration — solids removal before RO / IX

UF dominates new builds; MMF still owns most installed capacity. ABF and disc filters are niche. Cartridge filters appear in every plant as a 5 µm guard before the RO high-pressure pumps regardless of upstream choice.

Tech
Cut-off / mechanism
Strengths
Limitations
Multimedia filter (MMF)
~10 µm; sand + anthracite + garnet bed
Cheap, simple, robust, mature; wide TSS tolerance
Limited turbidity reduction (~70 %); SDI ≥ 3 typical; large footprint; high backwash water
Ultrafiltration (UF)
0.01 – 0.1 µm hollow-fibre membrane
Constant SDI < 3 even with feed swings; ~300 × better than MMF; removes bacteria; compact
Higher capex; CIP needed; backwash + chemical-enhanced backwash; chlorine-sensitive (PVDF tolerant)
Auto-Backwash Filter (ABF)
Continuous self-cleaning sand or screen
No service interruption for backwash; high TSS load tolerance; small backwash water fraction
Niche — wastewater reuse, intake water, high-TSS service; less common in clean municipal feeds
Microfiltration (MF)
0.1 – 10 µm membrane
Between MMF and UF; cheaper than UF
Doesn't reach SDI < 3 reliably; rarely used in pure-demin trains
Disc / screen filter
Stacked grooved discs or wedge wire
Compact, automatic flush; good for irrigation / cooling intake
Coarser than MMF; not a substitute for demin-grade pre-treatment
Cartridge filter (5 µm)
Pleated polypropylene cartridge
Final guard before HP pump; cheap; non-regenerable
Disposable; ΔP rises with loading; not a primary filter

Softening & scale control — protecting downstream membranes

Required when raw water hardness is high enough to scale the RO concentrate side despite antiscalant. Often skipped on low-hardness feeds — antiscalant alone handles it. Lime + IX combined for very hard brackish feeds.

Tech
What it removes
Best for
Cost / chemicals
SAC softener (Na form)
Hardness only (Ca, Mg → Na)
Moderate hardness, small-medium flow
NaCl brine regen; cheap salt; low capex
Weak-Acid Cation (WAC)
Alkalinity-hardness only (carbonate hardness)
Upstream of SAC for high-alkalinity feed; cuts SAC regen acid
Acid regen, but ~90 % efficient (vs ~50 % SAC)
Cold lime softening
Hardness, alkalinity, silica, Fe, Mn, radium, As
Hard brackish water, large flow, sludge handling acceptable
Lime + soda ash; large clarifier; sludge disposal
Hot Process Softener (HPS)
Same as cold lime + better silica (above 100 °C)
Power plants with waste steam, very high silica feed
Same chemicals + steam heat; vessel-built unit
Antiscalant only
Nothing — keeps Ca/Mg/Si in solution past saturation
Modern RO-first plants; capex-driven; moderate hardness
1 – 4 mg/L dose at RO feed; < $0.02/m³ permeate

Dechlorination — protecting RO & IX from oxidants

Free chlorine destroys polyamide RO membranes (lifetime in hours, not years) and oxidises IX resin. One of these MUST sit upstream of any membrane / resin contact.

Tech
Mechanism
Strengths
Limitations
Granular Activated Carbon (GAC)
Adsorption — also removes TOC, taste, odour
No moving chemicals; bonus organics removal; reliable
Bacterial growth in bed (de-chlorinated, organic-rich); replacement schedule
Sodium metabisulphite (SMBS)
Chemical reduction: Na₂S₂O₅ + Cl₂ → Na₂SO₄ + HCl
Compact, instant; no bed; preferred upstream of new RO trains
Dose ~1.8–3 mg/L per 1 mg/L Cl₂; pump reliability; under-dose = membrane failure
Sodium bisulphite (SBS)
Same chemistry as SMBS
Liquid form; less dust handling than SMBS
Same dose, same risk; storage stability shorter than SMBS
UV dechlorination
UV breaks Cl–N bonds; some free Cl₂ destruction
No chemicals; no bed; emerging in pharma / electronics
High UV dose (~60–600 mJ/cm²); not standard for industrial demin yet

Bulk demineralisation — the workhorse stage

New builds default to RO. IX still wins where feed TDS is genuinely low and water scarcity / reject disposal is a hard constraint. Modern plants run RO + EDI. Hybrid RO + IX appears for very high TDS feeds where IX is too costly alone and RO doesn't hit purity in two passes.

Tech
Strengths
Limitations
Best fit
IX SAC + SBA
Low capex; tolerant to feed swings; ~95–98 % recovery; outlet < 10 µS/cm
Concentrated acid + caustic on site (HSE); regen waste neutralisation
Low-TDS (< 400 ppm) feed, capex-tight legacy plants
IX SAC + DEG + SBA
Atmospheric degasser strips CO₂ between stages → cuts caustic regen consumption ~40 %
Extra vessel + tower + pump; takes plot space
Feeds with high alkalinity / CO₂ load (most groundwater)
IX WAC + SAC + DEG + SBA
WAC scavenges alkalinity-hardness cheaply (~90 % regen efficiency)
4 vessels in series; complex regen sequencing
Hard, alkaline feed where regen-cost optimisation matters
RO single-pass
No regen chemicals; modern; small footprint
Outlet 10–50 µS/cm — needs polishing for boiler / pharma
Most modern plants; combined with EDI / MB downstream
RO two-pass
Outlet < 5 µS/cm — sometimes skips polishing for low-purity duty
Higher capex + recovery loss; second-pass pump head
High-TDS feed, tighter outlet spec, no IX desired
High-Efficiency RO (HERO)
Operates at pH ~10 → silica solubility doubles; 90–95 % recovery
Caustic dose; needs WAC softening upstream; complex chemistry
Water-scarce sites with high silica feed
Closed-Circuit RO (CCRO)
Recirculates concentrate to feed; recovery 90 %+; no fixed array geometry
Newer tech; batch dynamics; specialist vendors
Scarce-water / high-TDS sites; brackish municipal
Nanofiltration (NF)
Selective rejection (passes monovalents, rejects divalents); lower pressure
Doesn't demineralise — it softens; ~50–90 % rejection of monovalents only
Selective duty (softening, partial demin, colour removal); rarely a full demin path
Hybrid RO + IX
RO drops bulk TDS, IX polishes — combines lower regen with high purity
Two skids of capex; both-streams maintenance
Very high TDS feed where 2-pass RO is borderline

Polishing — the last 10 µS/cm to 0.1

EDI has overtaken mixed bed in new builds for high-purity boiler feed water — no chemical regen, continuous service, smaller footprint. Mixed bed remains common in plants with existing IX pre-treatment, where the regen plant is already built. Separate cation / anion polishers are an older variant, occasionally retained for condensate polishing in power plants.

Tech
Strengths
Limitations
Best fit
EDI (electrodeionization)
No chemical regen; continuous; compact; same outlet purity as MB
Demands RO-quality feed (< 40 µS/cm, hardness < 1 ppm); higher capex
Modern RO-fed trains, no-chemicals goal — the new default
Mixed bed (regenerable)
Tolerates wider feed; lower capex; mature
Periodic acid + caustic regen; resin separation step is a reliability point
Existing IX plants, batch sites, lower-uptime requirements
Mixed bed (non-regenerable cartridge)
Cheapest install; no regen plant; replace cartridges
Cartridge replacement cost; not for high throughput
Lab water, small process duty, point-of-use polish
Cation + anion separate polishers
Independent regen; can balance loading
Two vessels in series; sodium leakage from cation limits anion outlet
Power-plant condensate polishing; legacy IX-only plants
UV (185 nm) for TOC
Breaks dissolved organics into ionic species → catches in downstream MB / EDI
Doesn't remove ions; only useful with ion polish downstream
Semiconductor / pharma TOC < 5 ppb requirements
→ Reference / Chemicals

What goes in.

A demin train is a chemical-handling plant in disguise. Coagulants and dechlorinators enter the feed; antiscalants and biocides protect the membranes; regen acids and caustics regenerate the resins; CIP chemicals clean everything. This is the full list by stage with typical doses — useful for sizing, audits, and HSE conversations.

Pre-treatment chemicals

Chemical
Purpose
Typical dose
Notes
Aluminium sulphate (alum)
Primary coagulant for clarification
10 – 60 mg/L (jar-test driven)
Drops pH; needs alkalinity or lime co-dose
Ferric chloride / ferric sulphate
Coagulant — broader pH range than alum
5 – 50 mg/L as Fe
Iron carryover into downstream stages — watch the spec
PolyDADMAC / polyamine
Cationic primary coagulant; small floc
0.5 – 5 mg/L
Carryover poisons RO membranes — strict shutoff at upset
Polyacrylamide (anionic)
Flocculant — bridges fine floc into settleable flocs
0.1 – 1 mg/L
Aged in solution 30+ min; over-dose stalls clarifier
Calcium hydroxide (lime)
Lime softening; pH lift; alkalinity
50 – 300 mg/L (as Ca(OH)₂)
Slurry handling; sludge generation; dust risk
Sodium carbonate (soda ash)
Adds carbonate for non-carbonate hardness in lime softening
0 – 200 mg/L
Used with lime when feed has non-carbonate hardness
Sulphuric acid / hydrochloric acid
pH trim before RO; alkalinity reduction
Dose to target pH 6.5–7.5 at RO feed
Concentrated acid handling; HSE-heavy
Sodium hydroxide
pH lift before second-pass RO; CIP high-pH
Dose to target pH 8.5–10 at 2nd-pass RO inlet
Boost rejection of CO₂ as carbonate

Dechlorination & oxidation control

Chemical
Purpose
Typical dose
Notes
Sodium metabisulphite (SMBS)
Reduce free chlorine before RO / IX
1.8 – 3 mg/L per 1 mg/L Cl₂ (with safety factor)
Solid → 5–10 % solution; ≥ 20–30 s pipe contact before membrane
Sodium bisulphite (SBS)
Same as SMBS, liquid form
Same equivalent dose
Shelf life shorter than SMBS solid
Sodium hypochlorite (NaOCl)
Pre-chlorination for biofouling control
0.5 – 2 mg/L free Cl₂ at intake
MUST be removed before RO/IX (see above) — common cause of membrane failure
Chlorine dioxide (ClO₂)
Alternative oxidant; better organics; lower disinfection by-products
0.1 – 0.5 mg/L
Generated on-site; handles up to ~0.5 mg/L without RO damage (but trace SBS still recommended)
Monochloramine
RO-tolerant biocide; long-residual
1 – 4 mg/L
Some membrane vendors warranty allows it; check spec sheet

RO chemistry — antiscalants, biocides, CIP

Chemical
Purpose
Typical dose
Notes
Antiscalant (phosphonates: HEDP, PBTC, ATMP)
Threshold inhibition of CaCO₃, CaSO₄, BaSO₄
1 – 4 mg/L (max ~8 mg/L)
Diluted day-tank with 7–10 day stability; verify against feed analysis
Antiscalant (polyacrylates / polymeric)
Crystal modification + dispersion; better silica handling
1 – 4 mg/L
Used where silica risk dominates; sometimes blended with phosphonate
Citric acid
RO CIP — low-pH clean for CaCO₃, iron
2 % w/w, pH 2–3, 30 °C max
Doesn't dissolve sulphate / silicate scale; ineffective for biofilm
Hydrochloric acid
RO CIP — stronger than citric for carbonate scale
0.2 % HCl, pH 1–2
Aggressive on stainless components; check skid metallurgy
Sodium hydroxide (RO CIP)
High-pH clean for organics, biofilm, silt
0.1 % NaOH, pH 11–12, 35 °C max
Always run high-pH first; sulphuric acid NOT used (CaSO₄ risk)
DBNPA (2,2-dibromo-3-nitrilopropionamide)
Non-oxidising biocide for RO CIP
10 – 30 mg/L during shutdown; up to 100 mg/L for shock
Membrane-compatible; degrades in days, no residual
Isothiazolinone
Storage / preservation biocide for off-line RO
Per vendor — typically 1 % preservative solution
Used for long-term lay-up; full flush before return to service

IX & mixed-bed regen chemicals

Chemical
Purpose
Typical strength
Notes
Hydrochloric acid (HCl)
Cation regen — SAC and MB cation
4 – 8 % HCl (from 32 % bulk)
Cleaner regen than H₂SO₄; no CaSO₄ scale risk; higher chemical cost
Sulphuric acid (H₂SO₄)
Cation regen — cheaper than HCl
0.7 – 1 % H₂SO₄ stepped; from 98 % bulk
Stepped concentration to avoid CaSO₄ precipitation; common in large plants
Sodium hydroxide (NaOH)
Anion regen — SBA and MB anion
4 – 5 % NaOH (from 50 % bulk)
Hot caustic (35–50 °C) for silica removal; injection eductor
Sodium chloride (NaCl)
SAC softener regen (Na form)
10 – 25 % brine
Cheap; no acid handling; pure brine produced from solid salt
Demin water for resin rinse / mix
Final rinse before service; resin re-mix in MB
Typically 5 – 8 bed-volumes
Conductivity tracking until back to spec

EDI chemistry — CIP only, no continuous chemicals

Chemical
Purpose
Typical strength
Notes
Citric acid (or HCl)
CIP — descale stack from upstream RO upset
2 % citric / 0.2 % HCl, pH ~2
Per vendor SOP; concentrate side first then diluate
Sodium hydroxide
CIP — organic / biofilm
1 % NaOH
Never on EDI without vendor approval — membrane chemistry varies
No regen chemicals in service
Continuous DC current does the work
This is the headline advantage over MB

Wastewater & ancillary

Chemical
Purpose
Typical use
Notes
Sulphuric acid (or HCl)
pH neutralisation of caustic regen waste
Stoichiometric to caustic load + control margin
Same acid feed line often reused from regen plant
Sodium hydroxide / lime
pH neutralisation of acid regen waste
Stoichiometric to acid load
Lime cheaper but produces sludge
SMBS (in waste)
Quench residual chlorine before discharge
1.8 – 3 mg/L per 1 mg/L residual Cl
If RO biocide / oxidant is in reject
Antifoam
Defoams degasser, equalisation tanks, neutralisation pit
0.5 – 5 mg/L as needed
Silicone-based; over-dose loads downstream
Storage tank N₂ blanket
Block CO₂ ingress in polished water storage
~1–5 mbar overpressure; low flow makeup
For storage targets < 0.1 µS/cm; pharma / power plants
→ Reference / Global ecosystem

Who builds what.

Names that show up on most major projects. Membrane and resin markets have consolidated hard over the last decade — DuPont absorbed FilmTec and Dow Water; Suez became Veolia Water Technologies.

→ UF / MF membranes
  • DuPont (IntegraPac, IntegraFlux)
  • Toray (HSU, HFU)
  • Suez (ZeeWeed, ZW)
  • Pall (Aria)
  • Inge (BASF)
  • Pentair / X-Flow
→ RO / NF membranes
  • DuPont (FilmTec)
  • Toray
  • LG Chem (Nanoh2o)
  • Hydranautics (Nitto)
  • Suez (AG, AK series)
  • CSM (Toray)
→ ABF / disc / screen filters
  • Veolia (AquaABF, ABW)
  • Aqua-Aerobic (TBF)
  • Amiad (ABF series)
  • Eaton (DCF, Hydac)
  • Forsta
  • Tekleen
→ Ion-exchange resin
  • Lanxess (Lewatit)
  • DuPont (Amberlite, AmberPack)
  • Purolite (Ecolab)
  • Mitsubishi Chemical (Diaion)
  • ResinTech
  • Thermax
→ EDI stacks
  • Suez (E-Cell MK series)
  • Evoqua (Ionpure)
  • DuPont (Omexell)
  • Pure Water Group
  • SnowPure (Electropure)
→ Degasser / membrane contactor
  • 3M / Liqui-Cel (membrane)
  • EuroWater
  • Veolia (vacuum + atmospheric)
  • Pure Water Group
→ Antiscalants & CIP chemicals
  • Avista (Vitec)
  • Veolia (PermaTreat / Hypersperse)
  • Solenis
  • Kurita (Genesys)
  • BWA (Flocon)
  • AWC (American Water Chemicals)
→ Coagulants & pre-treat chemicals
  • Kemira
  • SNF Floerger
  • BASF (Zetag, Magnafloc)
  • Solenis
  • Buckman
→ Pre-treatment + system EPC
  • Veolia Water Technologies
  • Xylem (Evoqua)
  • Ovivo
  • Aquatech
  • WesTech
  • Hyflux (legacy)
→ Pumps (HP, dosing, transfer)
  • Grundfos (CR, dosing)
  • KSB
  • Wanner Hydra-Cell
  • CAT Pumps
  • Sulzer (HP)
  • Milton Roy (dosing)
→ Analytical instrumentation
  • Hach (conductivity, pH, silica)
  • Mettler Toledo (Thornton — UPW)
  • Endress+Hauser
  • Yokogawa
  • Emerson (Rosemount)
  • Swan Analytical
→ Resin & CIP chemistry analysis
  • Purolite Tech Center
  • Lanxess Lab Services
  • AWC Lab
  • RGA Labs